How To Calculate Oxidation Number?

Assign oxidation numbers based on common rules

Free elements have oxidation number 0

Monatomic ions have oxidation number equal to their charge

Group 1 metals are usually +1

Group 2 metals are usually +2

Fluorine is always -1

Oxygen is usually -2

Hydrogen is usually +1

Sum of oxidation numbers in a neutral compound is 0

Sum of oxidation numbers in a polyatomic ion equals the ion charge

Use known oxidation numbers to solve for unknowns

Check for exceptions such as peroxides, hydrides, and compounds with fluorine

Verify the result by making the total charge balance correctly

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