How to Do PH Calculations?

Identify the solution type: strong acid, strong base, weak acid, weak base, buffer, or salt

Determine the concentration of the relevant hydrogen ion or hydroxide ion

For strong acids, use pH = -log[H+]

For strong bases, use pOH = -log[OH-]

Convert pOH to pH using pH + pOH = 14

For weak acids, use the acid dissociation constant Ka and an ICE table

For weak bases, use the base dissociation constant Kb and an ICE table

Use pH = -log[H+] after finding [H+]

Use pOH = -log[OH-] after finding [OH-]

For buffers, use the Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA])

For salt solutions, determine whether the ions hydrolyze in water

For polyprotic acids, calculate pH using the first dissociation if it dominates

For very dilute solutions, account for water autoionization if needed

Check significant figures in the final pH value

Verify whether the result should be acidic, neutral, or basic

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